WEBThe chemical structure of coal macerals is usually characterized by the presence of inorganic and organic sulfur. Inorganic sulfur consists mostly of iron sulfides, the socalled "pyritic sulfur," whereas organic sulfur is covalently bound to the carbon atoms of the coal macromolecule. Comminution o .
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WEBFeb 15, 2021 · A large amount of SOx will be produced in the combustion process of coal without desulfurization, which is the main factor causing air pollution, environmental damage and increase. Here, desulfurization of coal by chemical agents are summarized. Acid/alkali desulfurization and occur mainly through the chemical reaction .
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WEBThe FlueGas Desulfurization (FGD) process utilizes a set of technologies to remove sulfur dioxide (SO 2) from the flue gas emissions of coalfired power systems were developed as a response to the exhaust – flue gases – from fossil fuelburning plants, principally coalburning, that posed both an environmental and human health hazard.
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WEBJan 28, 2019 · Biological desulfurization processes as well as microbial coal desulfurization are called as one of precombustion coal desulfurization processes. The biodesulfurization can be described as microbiological sulfur removal from coal under ambient temperature and pressure without reducing calorific value (Kilbane et al. 2002).
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WEBOct 22, 2016 · A desulfurization method that by using microwave radiation assisted with alkali solution was applied to a highsulfur coking coal collected from Shanxi Province, north of China. First, the single factor experiments were involved to get the optimal microwave desulfurization conditions.
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WEBIn this paper, a twostep desulfurization process for highsulfur coal was investigated. Two Chinese coals with the addition of 10 wt % potassium hydroxide or sodium hydroxide were pyrolyzed under an atmosphere of nitrogen or hydrogen in a fixedbed reactor at 600 °C, and then the obtained chars were washed with hot water. The results indied that, .
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WEBJul 27, 2015 · 3. Flue Gas Desulfurization Technologies. Flue gas desulfurization is an efficient method for the reduction of the sulfur dioxide emissions. Citation 2 Many processes are available in the market, such as (a) wet scrubbers, (b) spray dry scrubbers, (c) sorbent injection, (d) regenerable processes, and (e) combined SO 2 /NO X removal processes. .
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WEBThe chemical structure of coal macerals is usually characterized by the presence of inorganic and organic sulfur. ... The microbial desulfurization of coal Adv Biochem Eng Biotechnol. 2014:142:14767. doi: /10_2013_178 ... So far the development of a microbial process for organic sulfur removal has shown to be much more difficult and ...
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WEBSynergetic, effective, and cheap desulfurization and denitration technologies will be our focus. Coal, as one of the most important sources of energy around the world due to the intensity of its exploiting and utilization, causes increasingly serious ecological problems, especially air pollution. Large amounts of pollutants are emitted during ...
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WEBThis paper briefly introduces various methods of coal desulfurization (physical desulphurization, chemical desulfurization, biological desulfurization, etc.) and analyzes some problems existing in each method. The principle and research process of friction electrostatic separation technology and high gradient magnetic separation technology in .
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WEBJan 15, 2022 · The desulfurization process was a process controlled by the gas film. Various factors had little effect on the desulfurization effect, and the removal rate was almost [167]. Y. Jia et al. established a mathematical model of the total sulfite oxidation process of ammonium sulfite and ammonium bisulfite in the ammonia .
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WEBAug 15, 2020 · Since the evaluation system for flue gas desulfurization technology of coalfired boilers for power plants is established at home and abroad, the indiors of denitrifiion and dedusting have not been included. ... As the flue gas desulfurization and denitrifiion process is continuously improved and innovated, the operating costs have ...
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WEBDec 15, 2023 · Photoalytic desulphurization is an emerging green technology that utilizes only solar energy and semiconductor heterogenous photoalysts (Fig. 7a b) to desulphurize fuel and coal organosulfur compounds under ambient conditions [80], [81]. Table 2 summarizes the latest literature on photoalytic desulphurization of coal and .
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WEBAmong the desulfurization processes, the oxidative desulfurization (ODS) process is a promising method to achieve very low and nearzero sulfur content of the fuel. In this process, sulfur compounds are converted to the corresponding sulfone by a alyst and in the presence of an oxidant. ... (MgAl, CuAl, and CoAl) on the GO as supports for ...
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WEBOct 1, 2001 · The results of coal desulfurization are given in Table experiments were carried out at methanol concentrations of 5 and 10%, at temperature of 120, 150 and 180°C, and at reaction times of 30, 60, and 90. min, with a solution to coal ratio of :1.. From these results, it can be seen that ash reduction ranges from 20 to 42%, total sulfur .
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WEBMay 19, 2001 · A detailed process model of the wet limestone flue gas desulfurization system has been presented. This model can be used to calculate indispensable parameters for estimating costs and next to minimize capital and operating costs. The process model describes most important stage of SO2 removal running in an absorber and a holding .
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WEBSep 14, 2019 · The transformation from pyrite to soluble FeSO 4 and Fe 2 (SO 4) 3 is the main reason for highsulfur coal desulfurization during the process of wetgrinding. Therefore, this investigation puts ...
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WEBMar 13, 2019 · Owing to the advantages such as a high desulfurization efficiency and proper adaptation to various types of coal, wet flue gas desulfurization (WFGD) has been widely adopted. ... The control system has also been improved to guarantee stability of the desulfurization process (Villanueva Perales et al. Citation 2010, Citation 2009; Wu, ...
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WEBSep 19, 2011 · Abstract Ammonium sulfate crystallization of ammoniabased flue gas desulphurization was studied. Experiments were conducted to study the influence of pH, temperature, and the fly ash content of the solution on ammonium sulfate crystallization. The fly ash promoted ammonium sulfate crystallization was investigated as well. The .
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WEBJul 30, 2016 · Process of desulphurization. Primarily, there are two options available for the removal of sulphur from the liquid steel. These are (i) by means of metalslag reaction, where the top slag is mixed intensively with the liquid steel, and (ii) by injection of metallic calcium (Ca) into liquid steel, where a precipitation of sulphides occurs. ...
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WEBOct 1, 2001 · Coal desulfurization is imperative to create clean coal and reducing harmful emissions during the combustion process. However, organic sulfur in coal is more difficult to remove than inorganic sulfur. Therefore, in this paper, a method of coal sample desulfurization using citric acid with microwave assisted was proposed, and .
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WEBMay 11, 2021 · Mechanism of Pyrite Microbial Desulfurization. The oxidation process of coal conversion is possible by microorganisms after getting influenced by the polyfunctional coal structure and this process usually depends on two main factors: size or shape of coal and surface properties of microorganisms (Konishi et al. 1990). The .
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WEBAug 30, 2023 · The main factor for the results above was that the desulfurization mechanisms were different. Therefore, the research of different desulfurization mechanisms is the main direction of future work. The consequence of this paper would provide data support for the selection of the desulfurization method for high sulfur coal.
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WEBDec 1, 2019 · Flue gas desulfurization gypsum (FGDG) is an industrial byproduct generated during the flue gas desulfurization process in coalfired power plants. Due to its abundance, chemical and physical properties, FGDG has been used in several beneficial appliions. However, during the past decade, the rate of beneficially used FGDG has .
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WEBThe FGD process. What is Flue Gas Desulfurization? Flue gas or "waste gas" as it is commonly known, is the exhaust byproduct of fossil fuel combustion. ... The biggest market for Flue Gas Desulfurization equipment is coalfired power plants. As of 2016, the International Energy Agency reports that there are approximately 62,000 thermal ...
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WEBMar 20, 1996 · A novel method for the chemical desulfurization of coal in relatively moderate conditions and short times is presented. Using concentrated hydroiodic acid as a desulfurizing agent and microwaves as the energy source, sulfate and pyritic sulfur are completely removed in 10 min. Moreover, for the lowrank coals studied, variable .
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WEBDesulfurization. Desulfurization or desulphurisation is a chemical process for the removal of sulfur from a material. This involves either the removal of sulfur from a molecule ( A=S → A:) or the removal of sulfur compounds from a mixture such as oil refinery streams. [1] These processes are of great industrial and environmental ...
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WEBSep 1, 2006 · It is the acid generated by absorption of the SO 2 into the liquid that drives the limestone dissolution process. Equation 2: CaCO 3 + 2H + Ca+2 + H 2 O + CO 2 ↑. Equations 1 and 2, when ...
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WEBNov 1, 2021 · 1. Introduction. Flue gas desulfurized gypsum mainly comes from thermal power plants, smelters, and largeenterprise boilers, and contains industrial byproducts produced through a wet desulfurization combustion process, where SO 2 gas and lime slurry react under strong oxidation conditions. The main component of this gypsum is .
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WEBIn this work, a new desulfurization process of high sulfur coal was designed and examined. The novel process involved pyrolysis of high sulfur coal at low temperature and then a dry magnetic separation. For testing the cleaning coal process, a Chinese high sulfur coal, Baisu coal was pyrolyzed in a fixed bed reactor from 400 to 700°C for .
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WEBJan 8, 2021 · Desulphurization is the removal of Sulphur Dioxide. The flue gas desulphurisation plants remove sulphur dioxides from the flue gas which is produced by boilers, furnaces, and other sources. Let us ...
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WEBAerosol formation is the primary problem of the wet ammoniabased desulphurization process. Experiments for the research of the aerosol formation characteristics were carry out on a coalfired boiler with wet ammoniabased desulphurization devices. The particle size distributions and number concentrations, morphologies and element compositions .
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WEBJul 10, 2020 · Zero emission of wastewater from coalfired power plants (CFPPs) is one of the pathways for cleaner electricity production. It is expected that lowcost and reliable zero liquid discharge (ZLD) of flue gas desulphurization (FGD) wastewater will be achieved by applying the forced circulation multieffect distillation and crystallization (FCMEDC) .
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WEBJul 11, 2022 · desulfurization (ADS), oxidative desulfurization (ODS), hydrodesulfurization (HDS), biodesulfurization (BDS), etc. Sulfides are directly ads orbed in to the adsorbent in the ADS step, and the surf ...
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