WEBNov 8, 2023 · Liquefaction is one of the several technologies available for biomass conversion, alongside processes like pyrolysis, gasifiion, and fermentation. The liquefaction process involves heating the biomass feedstock in the presence of a solvent or a alyst to break down the complex organic molecules into simpler, liquid .
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WEBJan 12, 1998 · A previous paper has shown that direct coal liquefaction in the absence of a alyst consists of two distinct stages which are readily distinguishable with an appropriate short contact time liquefaction reactor and thermogravimetric analysis. The first stage, an extraction of liquefaction solventsoluble material in the coal, is very .
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WEBNov 1, 2011 · Some researchers have reported that coliquefaction of biomass and coal under mild condition (about 350°C) has higher conversion and oil yield than those that would be predicted based on a simple ...
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WEBFeb 1, 2000 · Maximum conversion (98%) and maximum oil + gas yield (70%) from this coal were obtained by impregnating AHM onto coal and carrying out liquefaction in H2/tetralin system at 450 °C for 30 min.
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WEBAug 19, 2020 · The main objective of this paper is to carry out a technoeconomic evaluation for the direct coal liquefaction (DCL) process based on the two primary conversion options under consideration: (a) alytic coal liquefaction (CCL) – the use of nondonor solvents with added hydrogen pressure and (b) thermal coal liquefaction .
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WEBFeb 1, 2024 · It is well recognized that the high DCL reactivity of vitrinite of lowrank coals is ascribed to its structure characteristics. In specific, the aromatic units in these vitrinite are small, with 1–3 condensed rings, while the bridges and the side chains are generally composed of 1–4 carbon (C) and oxygen (O) atoms [11], [12]. Fig. 1 (a) is the structure .
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WEBAug 1, 2022 · The conversion routes of biomass are mainly summarized in Fig. biochemical conversion has been widely used for the production of biogas and ethanol fuel [18, 19], our article focuses on the thermochemical conversion routes in particular pyrolysis, hydrothermal liquefaction and gasifiion as these processes .
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WEBNov 1, 2017 · Coliquefaction technology of coal and biomass waste in preparation of oil has gained rapid increase in research interest [5]. Previous studies suggested a few benefits of the process. Firstly, the process can make use of hydrogen in biomass completely and thus reducing the hydrogen consumption and moderating the conditions .
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WEBDCL technology was invented by Friedrich Bergius in 1913. This technology directly produces liquid fuels from coal with the basic process that dissolves coal at high temperature and pressure and adds hydrogen to increase the hydrogen content [11]. DCL is the most efficient technology among the three current technologies.
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WEBOct 1, 2013 · Liquefaction of coal is a process whereby the macromolecular structure of coal is broken down by the addition of a solvent under moderate temperature and pressure to produce clean liquid fuels [1 ...
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WEBNov 1, 2022 · The cofeeding of coal and biomass and integrating high and lowtemperature processes can significantly improve the environmental performance of ICL [21], [22]. Coal to fuel ethanol (CTFE) is considered a promising substitute for gasoline in vehicles, but its environmental performances are much worse than those of fuel .
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WEBDec 1, 2003 · This paper reports detailed process designs and cost assessments for production of clean liquid fuels (methanol and dimethyl ether) by indirect coal liquefaction (ICL). Gasifiion of coal pro ...
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WEBJan 15, 2021 · Hydrothermal liquefaction is one of the most promising technologies to convert high moisture biomass into biofuels. However, understanding the liquefaction mechanism of different biomass fractions is still a challenge. The liquefaction of both lignin and cellulose is frequently studied, but the high diversity of biomass and processes .
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WEBMar 1, 2017 · With appropriate product upgrading, synthetic fuels produced from the DCL process can be directly used in the current motor engines. However, similar to other coal liquefaction processes, the DCL process has not been widely commercialized mainly because of economic uncertainty, high CO 2 emission, and high capital cost [1], [2].
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WEBJan 12, 1998 · A previous paper has shown that direct coal liquefaction in the absence of a alyst consists of two distinct stages which are readily ... A kinetic model for the liquefaction processes based on these observations is introduced. ... Direct liquefaction (DCL) processes and technology for coal and biomass conversion. 2011, 105154. .
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WEBSep 1, 2015 · The heavy organic components in the direct coal liquefaction residue (DCLR), such as asphaltene (AS) and preasphaltene (PA) have significant influence on the direct coal liquefaction (DCL) technology. In this paper, the molecular structure and size of two types of AS and PA from the DCLR of 6 t/d Shenhua process developing unit .
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WEBAug 1, 1984 · The use of highcarbonbased feeds to produce alternative fuels and valueadded chemicals is discussed. Basic conversion chemistry, chemical structures of coal and lignin biomass are discussed, followed by process technologies for direct liquefaction, liquid quality, process control and modeling, advantages and limitations, .
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WEBAdvances in Clean Hydrocarbon Fuel Processing || Direct liquefaction (DCL) processes and technology for coal and biomass conversion. Elsevier, pages 105154, 2011 ... (DCL) processes and technology for coal and biomass conversion Author. Burgess Clifford, C. Publisher. Elsevier Edition/series info. pages 105154, 2011 Year. 2011 .
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WEBMar 23, 2022 · Thermochemical conversion to produce liquid yield using biomass as a feedstock still facing constraints to directly use the produced biooil. High oxygenated compounds of biooil seek an upgrading process to enhance the quality. However, a number of upgrading processes can be considered to enhance the oil's quality.
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WEBOct 1, 2016 · Direct coal liquefaction (DCL) is an important way of coal conversion and is important to the global energy industry. In this paper, a typical liquefied coal–Naomaohu coal (NMHC)–was liquefied under mild conditions (400 °C, initial H 2 pressure of 3 MPa), and a NMHC conversion of % was obtained with an oil+gas yield of %. In the ...
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WEBJul 1, 1990 · Mechanism of hydrogen transfer and role of solvent during heatingup stage of direct coal liquefaction. Fuel Processing ... Kinetics and activation energy of solvent swelling of coal altered by an ultrasoniionenhanced process. Korean Journal ... Direct liquefaction (DCL) processes and technology for coal and biomass conversion. .
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WEBJul 27, 2022 · Fundamentals of HTL. Hydrothermal Liquefaction (HTL), also known as hydrous pyrolysis (Jazrawi 2014; Goswami et al. 2020b), is thermochemical conversion of biomass in a hightemperature pressurized environment (Yang and Yang 2019), in the presence of hot compressed water at subcritical conditions, mainly into a liquid product .
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WEBNov 1, 2023 · The thermochemical conversion of biomass, including liquefaction, torrefaction, pyrolysis, and gasifiion technologies, has attracted worldwide attention because these processes can convert biomass into alternative, sustainable, and ecofriendly fuels, such as biochar, biooil, and H 2 rich gas. However, there are some .
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WEBJul 1, 2006 · Direct coal liquefaction (DCL) converts solid coal (H/C ratio ≈ ) to liquid fuels (H/C ratio ≈ 2) by adding hydrogen at high temperature and pressures in the presence or absence of alyst.
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WEBIndirect liquefaction processes require first gasifying the solid feedstocks into a syngas. Therefore, while direct coal liquefaction (DCL) takes coal directly into a liquid phase, indirect coal liquefaction (ICL) consists of two major steps: (a) gasifiion to produce a synthesis gas (syngas); and (b) conversion of the carbon monoxide (CO) and hydrogen .
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WEBDirect liquefaction (DCL) processes and technology for coal and biomass conversion. 2011, 105154. ... A new process for alytic liquefaction of coal using dispersed MoS2 alyst generated in situ with added H2O. Fuel 2000, 79 ... Mechanochemical effects in coal conversion. 1. Coal hydrogenation in gaseous hydrogen aided by mechanical .
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WEBDue to insecurity in the crude oil supply and global warming, various alternative technologies for fuel production are being investigated. In this project, indirect, direct, and hybrid liquefaction routes are investigated for production of transportation fuels from coal and biomass. Indirect coal liquefaction (ICL) and direct coal liquefaction (DCL) .
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WEBApr 29, 2024 · Biomass hydrothermal liquefaction (HTL) is a conversion technology that utilizes hightemperature and highpressure hydrothermal conditions to convert biomass into liquid fuels and chemicals. This review introduces all aspects of biomass HTL from system process parameters to reaction mechanism pathways and product control .
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WEBNov 1, 2019 · Therefore, the development of processes that would be able to convert biomass under milder reaction conditions (below 20 bar [101]) would be a step forward for the commercialization of lignocellulosic biomass conversion through liquefaction. However, the desired temperature range required for the process, 200–400 °C, .
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WEBJan 30, 2020 · Gasifiion is a thermochemical conversion process in which carbonaceous substances such as biomass are partially ... Hein KRG, Bemtgen JM (1998) EU clean coal technologycocombustion of coal and biomass. Fuel Process Technol 54:159–169. ... (2011) Hydrothermal liquefaction of biomass: a review of subcritical .
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WEBSep 12, 2021 · Figure : Next thermochemical conversion method of biomass – direct liquefaction. (The fourth, combustion, is not really a thermochemical conversion of biomass). Credit: Dr. Caroline B. Clifford. There are differences for each of the thermal processes, as described in Lesson 5. Here we focus on direct liquefaction.
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WEBFeb 5, 2014 · Abstract. The frontend design of a direct coal liquefaction process for the conversion of lignite into coal liquids by solvent extraction was investigated. The experimental work focused on ...
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WEBBiomass is often referred to as a carbon–neutral energy source, and it has a role in reducing fossil fuel depletion. In addition, biomass can be converted efficiently into various forms of biofuels. The biomass conversion processes involve several thermochemical, biochemical, and hydrothermal methods for biomass treatment integration. The most .
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WEBJan 1, 2017 · Direct coal liquefaction (DCL) is one of the major technologies for alytic conversion of coal to obtain liquid fuels via hydrogenation and heteroatom removal [3][4] [5]. DCL residue mainly ...
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